Cyclotrimerisation of isocyanates catalysed by low-coordinate Mn(II) and Fe(II) m-terphenyl complexes

Article English OPEN
Sharpe, Helen R. ; Geer, Ana M. ; Williams, Huw E.L. ; Blundell, Toby J. ; Lewis, William ; Blake, Alexander J. ; Kays, Deborah L. (2016)

Two- and three-coordinate m-terphenyl complexes of manganese and iron are efficient catalysts for the selective cyclotrimerisation of primary aliphatic isocyanates affording isocyanurates in short reaction times and under mild conditions.
  • References (22)
    22 references, page 1 of 3

    1 a) J. M. Kenny, L. Torre and L. M. Chiacchiarelli, J. Appl. Polym. Sci., 2015, 132, 42750; b) G. Wegener, M. Brandt, L. Duda, J. Hofmann, B. Klesczewski, D. Koch, R.-J. Kumpf, H. Orzesek, H.-G. Pirkl, C. Six, C. Steinlein and M. Weisbeck, Appl. Catal., A, 2001, 221, 303.

    2 a) E. Preis, N. Schindler, S. Adrian and U. Scherf, ACS Macro Letters, 2015, 4, 1268; b) Y. Zhang, S. N. Riduan and J. Y. Ying, Chem. Eur. J., 2009, 15, 1077.

    3 M. Mascal, I. Yakovlev, E. B. Nikitin and J. C. Fettinger, Angew. Chem. Int. Ed., 2007, 46, 8782.

    4 a) P. Gibbons, D. Love, T. Craig, C. Budke, Vet. Parasitol., 2016, 218, 1; b) A. Bosco, L. Rinaldi, G. Cappelli, A. Saratsis, L. Nisoli, G. Cringoli, Vet. Parasitol., 2015, 212, 408; c) A. P. Murray and M. J. Miller, J. Org. Chem., 2003, 68, 191; d) M. Ghosh, M. J. Miller, J. Org. Chem., 1994, 59, 1020.

    5 Y. Taguchi, I. Shibuya, M. Yasumoto, T. Tsuchiya and K. Yonemoto, Bull. Chem. Soc. Jpn., 1990, 63, 3486.

    6 a) D. Heift, Z. Benkő, H. Grützmacher, A. R. Jupp and J. M. Goicoechea, Chem. Sci., 2015, 6, 4017; b) J. N. Gibb and J. M. Goodman, Org. Biomol. Chem., 2013, 11, 90; c) S. M. Raders and J. G. Verkade, J. Org. Chem., 2010, 75, 5308; d) Z. Pusztai, G. Vlad, A. Bodor, I. T. Horváth, H. J. Laas, R. Halpaap and F. U. Richter, Angew. Chem. Int. Ed., 2006, 45, 107; e) J.-S. Tang and J. G. Verkade, Angew. Chem. Int. Ed., 1993, 32, 896.

    7 H. A. Duong, M. J. Cross and J. Louie, Org. Lett., 2004, 6, 4679.

    8 a) W. Yi, J. Zhang, L. Hong, Z. Chen and X. Zhou, Organometallics, 2011, 30, 5809; b) X. Zhu, J. Fan, Y. Wu, S. Wang, L. Zhang, G. Yang, Y. Wei, C. Yin, H. Zhu, S. Wu and H. Zhang, Organometallics, 2009, 28, 3882; c) W.-K. Wong, L. Zhang, W.-T. Wong, F. Xue and T. C. W. Mak, J. Chem. Soc., Dalton Trans., 1999, 615.

    9 a) M. K. Barman, A. Baishya, T. Peddarao and S. Nembenna, J. Organomet. Chem., 2014, 772-773, 265; b) L. Orzechowski and S. Harder, Organometallics 2007, 26, 2144; c) S. R. Foley, Y. Zhou, G. P. A. Yap and D. S. Richeson, Inorg. Chem., 2000, 39, 924; d) S. R. Foley, G. P. A. Yap and D. S. Richeson, Organometallics, 1999, 18, 4700.

    10 J. F. Villa and H. B. Powell, Synth. React. Inorg. Metal-Org. Chem. , 1976, 6, 59.

  • Metrics
    No metrics available
Share - Bookmark