1,4-diazoniabicyclo 2.2.2 octane aquabis(oxalato-?² O,O')copper(II) dihydrate
Keene, Tony D.
Hursthouse, Michael B.
Price, Daniel J.
- Publisher: International Union of Crystallography
The title compound, (C6H14N2)[Cu(C2O4)(2)(H2O)].2H(2)O, crystallizes in the space group P (1) over bar. In the solid state, the [Cu(ox)(2)(H2O)](2-) units (ox is oxalate, C2O4) dimerize to give a tetragonally distorted CuO6 coordination environment. Extensive hydrogen bonding between the oxalate, the coordinated water, the 1,4-diazoniabicyclo[2.2.2]octane dications ([dabcoH(2)](2+)) and the water of crystallization determines the crystal packing.