Stratospheric Air Sub-sampler (SAS) and its application to analysis of Δ17O(CO2) from small air samples collected with an AirCore

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Mrozek, Dorota Janina ; Veen, Carina ; Hofmann, Magdalena E. G. ; Chen, Huilin ; Kivi, Rigel ; Heikkinen, Pauli ; Röckmann, Thomas (2016)

We present the set-up and a scientific application of the Stratospheric Air Sub-sampler (SAS), a device to collect and to store the vertical profile of air collected with an AirCore (Karion et al., 2010) in numerous sub-samples for later analysis in the laboratory. The SAS described here is a 20 m long 1/4 inch stainless steel tubing that is separated by eleven valves to divide the tubing into 10 identical segments, but it can be easily adapted to collect smaller or larger samples. In the collection phase the SAS is directly connected to the outlet of an optical analyzer that measures the mole fractions of CO<sub>2</sub>, CH<sub>4</sub> and CO from an AirCore sampler. The stratospheric part (or if desired any part of the AirCore air) is then directed through the SAS. When the SAS is filled with the selected air, the valves are closed and the vertical profile is maintained in the different segments of the SAS. The segments can later be analysed to retrieve vertical profiles of other trace gas signatures that require slower instrumentation. As an application, we describe the coupling of the SAS to an analytical system to determine the <sup>17</sup>O excess of CO<sub>2</sub>, which is a tracer for photochemical processing of stratospheric air. For this purpose the analytical system described by Mrozek et al. (2015) was adapted for analysis of air directly from the SAS. The performance of the coupled system is demonstrated for a set of air samples from an AirCore flight in November 2014 near Sodankylä, Finland. The standard error for a 25 mL air sample at stratospheric CO<sub>2</sub> mole fraction is 0.56 ‰ (1<i>σ</i>) for <i>δ</i><sup>17</sup>O and 0.03 ‰ (1<i>σ</i>) for both <i>δ</i><sup>18</sup>O and <i>δ</i><sup>13</sup>C. Measured Δ<sup>17</sup>O(CO<sub>2</sub>) values show a clear correlation with N<sub>2</sub>O in agreement with already published data.
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