Observations of Particles at their Formation Sizes in Beijing, China

Other literature type English OPEN
Jayaratne, Rohan ; Pushpawela, Buddhi ; He, Congrong ; Gao, Jian ; Hui, Li ; Morawska, Lidia (2017)

New particle formation (NPF) has been observed in many highly polluted environments of South-East Asia, including Beijing, where the extent of its contribution to intense haze events is still an open question. Estimated characteristics of NPF events, such as their starting times and formation and growth rates of particles, are very different when the measurements are restricted to particles in larger size ranges. In order to understand the very first steps of particle formation, we used a neutral cluster and air ion spectrometer (NAIS) to investigate particle characteristics at sizes exactly where atmospheric nucleation and cluster activity occurs. Observations over a continuous three-month period in Beijing showed 26 NPF events. These events generally coincided with periods with relatively clean air when the wind direction was from the less-industrialized north. No NPF were observed when the daily mean PM<sub>2.5</sub> concentration exceeded 43&thinsp;µg&thinsp;m<sup>-3</sup>, which was the upper threshold for particle formation in Beijing. The fraction of particles that are charged in the size range 2&ndash;42 nm was normally about 15%. However, this fraction increased to 20&ndash;30% during haze events and decreased to below 10&thinsp;% during NPF events. With the NAIS, we determined the starting times of NPF very precisely to a greater accuracy than has been possible in Beijing before and provided a temporal distribution of NPF events with a maximum at about 8.30 am. Particle formation rates varied between 10&ndash;36&thinsp;cm<sup>-3</sup>&thinsp;s<sup>-1</sup>. Particle growth rates were estimated to be in the range 0.5&ndash;9.0&thinsp;nm&thinsp;h<sup>-1</sup>. These results are more reliable than previous studies in Beijing as the measurements were conducted for the first time at the exact sizes where clusters form into particles and provide useful insight into the formation of haze events.
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