(R)-4-MENTHEN-3-ОNE IN THE REACTIONS 1,2- AND 1,4-ADDITION OF MAGNESIUM- AND ORGANOLITHIUM REAGENTS

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Ишмуратов, Гумер Юсупович ; Баннова, Анна Владимировна ; Латыпова, Эльвира Разифовна ; Муслухов, Ринат Рафаисович ; Тухватшин, Вадим Салаватович ; Талипов, Рифкат Фаатович (2013)
  • Publisher: Altai State University
  • Journal: Khimiia rastitel'nogo syr'ia (Chemistry of plant raw material) (issn: 1029-5143, eissn: 1029-5151)
  • Related identifiers: doi: 10.14258/jcprm.1302073
  • Subject: (R)-4-menthen-3-оne, adducts of 1,2- and 1,4-addition, organomagnesium reagent, organolithium reagent | (R)-4-ментен-3-он, аддукты 1,2- и 1,4-присоединения, магнийорганический реагент, литийорганический реагент

The influence of temperature, nature of magnesium and organolithium reagents, solvent, catalyst on the processes 1,2- and 1,4-addition to the enone system of (R)-4-Menten-3-one were studied. Optimal conditions for the synthesis of 1,2 - and 1,4-adducts were identified.
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