publication . Article . 2014

ФОСФОРИЛИРОВАНИЕ ПОЛИПРЕНОЛОВ ПРОИЗВОДНЫМИ 1,3,2-ДИОКСАФОСФОРИНАНОВ

Маленковская, Маргарита Александровна; Расадкина, Елена Николаевна; Пугашова, Нина Михайловна; Нифантьев, Эдуард Евгеньевич;
Open Access Russian
  • Published: 08 Sep 2014 Journal: Khimiia rastitel'nogo syr'ia (Chemistry of plant raw material) (issn: 1029-5143, eissn: 1029-5151, Copyright policy)
  • Publisher: Altai State University
Abstract
Phosphorylation of polyprenols by chloro- and amidocyclophosphites on hydroxyl group was studied. Phosphocyclophosphites , phosphates and thiophosphates of polyprenol were obtained  and chromotographically isolated. It was shown that they are formed as conformers and cis-trans isomers. With the aim of obtaining original homocholines, which exist in thiono- and thioloforms, the alkylation of trimethylamine by polyprenyl-2-thio-1,3,2-dioxaphosphorinane were performed, but we failed to separate thiono- and thioloforms. The ammonium salt as thionoform was obtained by the hydrolysis of the same thiophosphate in the presence of triethylamine. The structures of all syn...
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