publication . Article . 2014


Маленковская, Маргарита Александровна; Расадкина, Елена Николаевна; Пугашова, Нина Михайловна; Нифантьев, Эдуард Евгеньевич;
Open Access Russian
  • Published: 08 Sep 2014 Journal: Khimiia rastitel'nogo syr'ia (Chemistry of plant raw material) (issn: 1029-5143, eissn: 1029-5151, Copyright policy)
  • Publisher: Altai State University
Phosphorylation of polyprenols by chloro- and amidocyclophosphites on hydroxyl group was studied. Phosphocyclophosphites , phosphates and thiophosphates of polyprenol were obtained  and chromotographically isolated. It was shown that they are formed as conformers and cis-trans isomers. With the aim of obtaining original homocholines, which exist in thiono- and thioloforms, the alkylation of trimethylamine by polyprenyl-2-thio-1,3,2-dioxaphosphorinane were performed, but we failed to separate thiono- and thioloforms. The ammonium salt as thionoform was obtained by the hydrolysis of the same thiophosphate in the presence of triethylamine. The structures of all syn...
Powered by OpenAIRE Open Research Graph
Any information missing or wrong?Report an Issue