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Other research product . 2020

Enhanced growth rate of atmospheric particles from sulfuric acid

Stolzenburg, Dominik; Simon, Mario; Ranjithkumar, Ananth; Kürten, Andreas; Lehtipalo, Katrianne; Gordon, Hamish; Ehrhart, Sebastian; +71 Authors
Open Access
English
Published: 25 Jun 2020
Abstract
In the present-day atmosphere, sulfuric acid is the most important vapour for aerosol particle formation and initial growth. However, the growth rates of nanoparticles (<10 nm) from sulfuric acid remain poorly measured. Therefore, the effect of stabilizing bases, the contribution of ions and the impact of attractive forces on molecular collisions are under debate. Here, we present precise growth rate measurements of uncharged sulfuric acid particles from 1.8 to 10 nm, performed under atmospheric conditions in the CERN (European Organization for Nuclear Research) CLOUD chamber. Our results show that the evaporation of sulfuric acid particles above 2 nm is negligible, and growth proceeds kinetically even at low ammonia concentrations. The experimental growth rates exceed the hard-sphere kinetic limit for the condensation of sulfuric acid. We demonstrate that this results from van der Waals forces between the vapour molecules and particles and disentangle it from charge–dipole interactions. The magnitude of the enhancement depends on the assumed particle hydration and collision kinetics but is increasingly important at smaller sizes, resulting in a steep rise in the observed growth rates with decreasing size. Including the experimental results in a global model, we find that the enhanced growth rate of sulfuric acid particles increases the predicted particle number concentrations in the upper free troposphere by more than 50 %.
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Funded byView all
NSF| Collaborative Research: Cosmics Leaving OUtdoor Droplets (CLOUD) Consortium Membership
Project
  • Funder: National Science Foundation (NSF)
  • Project Code: 1801280
  • Funding stream: Directorate for Geosciences | Division of Atmospheric and Geospace Sciences
,
EC| CLOUD-MOTION
Project
CLOUD-MOTION
CLOUD-MObility, Training and InnOvation Network
  • Funder: European Commission (EC)
  • Project Code: 764991
  • Funding stream: H2020 | MSCA-ITN-ETN
,
AKA| Oxidised organic vapours in the atmosphere: From fluxes to chemical formation mechanisms and impacts, SNSF| CLOUD Infrastructure project
Project
  • Funder: Swiss National Science Foundation (SNSF)
  • Project Code: 20FI20_172622
  • Funding stream: Infrastructure | Research Infrastructure
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