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Simultaneous detection of C2H6, CH4, and δ13C-CH4 using optical feedback cavity-enhanced absorption spectroscopy in the mid-infrared region: towards application for dissolved gas measurements
Simultaneous detection of C2H6, CH4, and δ13C-CH4 using optical feedback cavity-enhanced absorption spectroscopy in the mid-infrared region: towards application for dissolved gas measurements
Simultaneous measurement of C2H6 and CH4 concentrations, and of the δ13C-CH4 isotope ratio is demonstrated using a cavity-enhanced absorption spectroscopy technique in the mid-IR region. The spectrometer is compact and has been designed for field operation. It relies on optical-feedback-assisted injection of 3.3 µm radiation from an interband cascade laser (ICL) into a V-shaped high-finesse optical cavity. A minimum absorption coefficient of 2.8×10-9 cm−1 is obtained in a single scan (0.1 s) over 0.7 cm−1. Precisions of 3 ppbv, 11 ppbv, and 0.08 ‰ for C2H6, CH4, and δ13C-CH4, respectively, are achieved after 400 s of integration time. Laboratory calibrations and tests of performance are reported here. They show the potential for the spectrometer to be embedded in a sensor probe for in situ measurements in ocean waters, which could have important applications for the understanding of the source and fate of hydrocarbons from the seabed and in the water column.
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citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).0 popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.Average influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).Average impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.Average citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).0 popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.Average influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).Average impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.Average
Citations provided by BIP!Popularity provided by BIP!Simultaneous measurement of C2H6 and CH4 concentrations, and of the δ13C-CH4 isotope ratio is demonstrated using a cavity-enhanced absorption spectroscopy technique in the mid-IR region. The spectrometer is compact and has been designed for field operation. It relies on optical-feedback-assisted injection of 3.3 µm radiation from an interband cascade laser (ICL) into a V-shaped high-finesse optical cavity. A minimum absorption coefficient of 2.8×10-9 cm−1 is obtained in a single scan (0.1 s) over 0.7 cm−1. Precisions of 3 ppbv, 11 ppbv, and 0.08 ‰ for C2H6, CH4, and δ13C-CH4, respectively, are achieved after 400 s of integration time. Laboratory calibrations and tests of performance are reported here. They show the potential for the spectrometer to be embedded in a sensor probe for in situ measurements in ocean waters, which could have important applications for the understanding of the source and fate of hydrocarbons from the seabed and in the water column.