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apps Other research product2018 English EC | ECLISE, EC | HELIXEC| ECLISE ,EC| HELIXAuthors: Papadimitriou, Lamprini V.; Koutroulis, Aristeidis G.; Grillakis, Manolis G.; Tsanis, Ioannis K.;Papadimitriou, Lamprini V.; Koutroulis, Aristeidis G.; Grillakis, Manolis G.; Tsanis, Ioannis K.;Global climate model (GCM) outputs feature systematic biases that render them unsuitable for direct use by impact models, especially for hydrological studies. To deal with this issue, many bias correction techniques have been developed to adjust the modelled variables against observations, focusing mainly on precipitation and temperature. However, most state-of-the-art hydrological models require more forcing variables, in addition to precipitation and temperature, such as radiation, humidity, air pressure, and wind speed. The biases in these additional variables can hinder hydrological simulations, but the effect of the bias of each variable is unexplored. Here we examine the effect of GCM biases on historical runoff simulations for each forcing variable individually, using the JULES land surface model set up at the global scale. Based on the quantified effect, we assess which variables should be included in bias correction procedures. To this end, a partial correction bias assessment experiment is conducted, to test the effect of the biases of six climate variables from a set of three GCMs. The effect of the bias of each climate variable individually is quantified by comparing the changes in simulated runoff that correspond to the bias of each tested variable. A methodology for the classification of the effect of biases in four effect categories (ECs), based on the magnitude and sensitivity of runoff changes, is developed and applied. Our results show that, while globally the largest changes in modelled runoff are caused by precipitation and temperature biases, there are regions where runoff is substantially affected by and/or more sensitive to radiation and humidity. Global maps of bias ECs reveal the regions mostly affected by the bias of each variable. Based on our findings, for global-scale applications, bias correction of radiation and humidity, in addition to that of precipitation and temperature, is advised. Finer spatial-scale information is also provided, to suggest bias correction of variables beyond precipitation and temperature for regional studies.
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For further information contact us at helpdesk@openaire.euapps Other research product2018 English EC | SWITCH-ONEC| SWITCH-ONPugliese, Alessio; Persiano, Simone; Bagli, Stefano; Mazzoli, Paolo; Parajka, Juraj; Arheimer, Berit; Capell, René; Montanari, Alberto; Blöschl, Günter; Castellarin, Attilio;Our study develops and tests a geostatistical technique for locally enhancing macro-scale rainfall–runoff simulations on the basis of observed streamflow data that were not used in calibration. We consider Tyrol (Austria and Italy) and two different types of daily streamflow data: macro-scale rainfall–runoff simulations at 11 prediction nodes and observations at 46 gauged catchments. The technique consists of three main steps: (1) period-of-record flow–duration curves (FDCs) are geostatistically predicted at target ungauged basins, for which macro-scale model runs are available; (2) residuals between geostatistically predicted FDCs and FDCs constructed from simulated streamflow series are computed; (3) the relationship between duration and residuals is used for enhancing simulated time series at target basins. We apply the technique in cross-validation to 11 gauged catchments, for which simulated and observed streamflow series are available over the period 1980–2010. Our results show that (1) the procedure can significantly enhance macro-scale simulations (regional LNSE increases from nearly zero to ≈0.7) and (2) improvements are significant for low gauging network densities (i.e. 1 gauge per 2000 km2).
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For further information contact us at helpdesk@openaire.euapps Other research product2019 English EC | ECOADAPTEC| ECOADAPTAuthors: Fernández, Alfonso; Muñoz, Ariel; González-Reyes, Álvaro; Aguilera-Betti, Isabella; +8 AuthorsFernández, Alfonso; Muñoz, Ariel; González-Reyes, Álvaro; Aguilera-Betti, Isabella; Toledo, Isadora; Puchi, Paulina; Sauchyn, David; Crespo, Sebastián; Frene, Cristian; Mundo, Ignacio; González, Mauro; Vignola, Raffaele;Streamflow in south-central Chile (SCC, ∼ 37–42∘ S) is vital for agriculture, forestry production, hydroelectricity, and human consumption. Recent drought episodes have generated hydrological deficits with damaging effects on these activities. This region is projected to undergo major reductions in water availability, concomitant with projected increases in water demand. However, the lack of long-term records hampers the development of accurate estimations of natural variability and trends. In order to provide more information on long-term streamflow variability and trends in SCC, here we report findings of an analysis of instrumental records and a tree-ring reconstruction of the summer streamflow of the Río Imperial (∼ 37∘ 40′ S–38∘ 50′ S). This is the first reconstruction in Chile targeted at this season. Results from the instrumental streamflow record (∼ 1940 onwards) indicated that the hydrological regime is fundamentally pluvial with a small snowmelt contribution during spring, and evidenced a decreasing trend, both for the summer and the full annual record. The reconstruction showed that streamflow below the average characterized the post-1980 period, with more frequent, but not more intense, drought episodes. We additionally found that the recent positive phase of the Southern Annular Mode has significantly influenced streamflow. These findings agree with previous studies, suggesting a robust regional signal and a shift to a new hydrological scenario. In this paper, we also discuss implications of these results for water managers and stakeholders; we provide rationale and examples that support the need for the incorporation of tree-ring reconstructions into water resources management.
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For further information contact us at helpdesk@openaire.euapps Other research product2019 English EC | EARTH2OBSERVEEC| EARTH2OBSERVEAuthors: Bhuiyan, Md Abul Ehsan; Nikolopoulos, Efthymios I.; Anagnostou, Emmanouil N.; Quintana-Seguí, Pere; +1 AuthorsBhuiyan, Md Abul Ehsan; Nikolopoulos, Efthymios I.; Anagnostou, Emmanouil N.; Quintana-Seguí, Pere; Barella-Ortiz, Anaïs;This study investigates the use of a nonparametric, tree-based model, quantile regression forests (QRF), for combining multiple global precipitation datasets and characterizing the uncertainty of the combined product. We used the Iberian Peninsula as the study area, with a study period spanning 11 years (2000–2010). Inputs to the QRF model included three satellite precipitation products, CMORPH, PERSIANN, and 3B42 (V7); an atmospheric reanalysis precipitation and air temperature dataset; satellite-derived near-surface daily soil moisture data; and a terrain elevation dataset. We calibrated the QRF model for two seasons and two terrain elevation categories and used it to generate ensemble for these conditions. Evaluation of the combined product was based on a high-resolution, ground-reference precipitation dataset (SAFRAN) available at 5 km 1 h−1 resolution. Furthermore, to evaluate relative improvements and the overall impact of the combined product in hydrological response, we used the generated ensemble to force a distributed hydrological model (the SURFEX land surface model and the RAPID river routing scheme) and compared its streamflow simulation results with the corresponding simulations from the individual global precipitation and reference datasets. We concluded that the proposed technique could generate realizations that successfully encapsulate the reference precipitation and provide significant improvement in streamflow simulations, with reduction in systematic and random error on the order of 20–99 and 44–88 %, respectively, when considering the ensemble mean.
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For further information contact us at helpdesk@openaire.euapps Other research product2019 English EC | SOILTRECEC| SOILTRECAndrianaki, Maria; Shrestha, Juna; Kobierska, Florian; Nikolaidis, Nikolaos P.; Bernasconi, Stefano M.;In this study, we investigated the application and the transferability of the Soil Water and Assessment Tool (SWAT) in a partly glacierized Alpine catchment characterized by extreme climatic conditions and steep terrain. The model was initially calibrated for the 10 km2 watershed of the Damma glacier Critical Zone Observatory (CZO) in central Switzerland using monitoring data for the period of 2009–2011 and then was evaluated for 2012–2013 in the same area. Model performance was found to be satisfactory against both the Nash–Sutcliffe criterion (NS) and a benchmark efficiency (BE). The transferability of the model was assessed by using the parameters calibrated on the small watershed and applying the model to the approximately 100 km2 catchment that drains into the hydropower reservoir of the Göscheneralpsee and includes the Damma glacier CZO. Model results were compared to the reservoir inflow data from 1997 to 2010 and it was found that the model predicted successfully snowmelt timing and autumn recession but could not accurately capture the peak flow for certain years. Runoff was slightly overestimated from late May to June, when it is dominated by snowmelt. Finally, we investigated the response of the greater catchment to climate change using three different climate change scenarios, and the results were compared to those of a previous study, where two different hydrological models, PREVAH and ALPINE3D, were used. The methodology presented here, where SWAT is calibrated for a small watershed and then applied for a bigger area with similar climatic conditions and geographical characteristics, could work even under extreme conditions like ours. However, greater attention should be given to the differences between glacier melt and snowmelt dynamics. In conclusion, this assessment test on the transferability of SWAT on different scales gave valuable information about the strengths and weaknesses of the model when it was applied under conditions different to those under which it was calibrated.
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For further information contact us at helpdesk@openaire.euapps Other research product2018 English EC | CLIMBEC| CLIMBAuthors: Mascaro, G.; Piras, M.; Deidda, R.; Vivoni, E. R.;Mascaro, G.; Piras, M.; Deidda, R.; Vivoni, E. R.;The water resources and hydrologic extremes in Mediterranean basins are heavily influenced by climate variability. Modeling these watersheds is difficult due to the complex nature of the hydrologic response as well as the sparseness of hydrometeorological observations. In this work, we present a strategy to calibrate a distributed hydrologic model, known as TIN-based Real-time Integrated Basin Simulator (tRIBS), in the Rio Mannu basin (RMB), a medium-sized watershed (472.5 km2) located in an agricultural area in Sardinia, Italy. In the RMB, precipitation, streamflow and meteorological data were collected within different historical periods and at diverse temporal resolutions. We designed two statistical tools for downscaling precipitation and potential evapotranspiration data to create the hourly, high-resolution forcing for the hydrologic model from daily records. Despite the presence of several sources of uncertainty in the observations and model parameterization, the use of the disaggregated forcing led to good calibration and validation performances for the tRIBS model, when daily discharge observations were available. The methodology proposed here can be also used to disaggregate outputs of climate models and conduct high-resolution hydrologic simulations with the goal of quantifying the impacts of climate change on water resources and the frequency of hydrologic extremes within medium-sized basins.
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For further information contact us at helpdesk@openaire.euapps Other research product2019 English EC | MARSOLEC| MARSOLRodríguez-Escales, Paula; Canelles, Arnau; Sanchez-Vila, Xavier; Folch, Albert; Kurtzman, Daniel; Rossetto, Rudy; Fernández-Escalante, Enrique; Lobo-Ferreira, João-Paulo; Sapiano, Manuel; San-Sebastián, Jon; Schüth, Christoph;Managed aquifer recharge (MAR) can be affected by many risks. Those risks are related to different technical and non-technical aspects of recharge, like water availability, water quality, legislation, social issues, etc. Many other works have acknowledged risks of this nature theoretically; however, their quantification and definition has not been developed. In this study, the risk definition and quantification has been performed by means of “fault trees” and probabilistic risk assessment (PRA). We defined a fault tree with 65 basic events applicable to the operation phase. After that, we have applied this methodology to six different managed aquifer recharge sites located in the Mediterranean Basin (Portugal, Spain, Italy, Malta, and Israel). The probabilities of the basic events were defined by expert criteria, based on the knowledge of the different managers of the facilities. From that, we conclude that in all sites, the perception of the expert criteria of the non-technical aspects were as much or even more important than the technical aspects. Regarding the risk results, we observe that the total risk in three of the six sites was equal to or above 0.90. That would mean that the MAR facilities have a risk of failure equal to or higher than 90 % in the period of 2–6 years. The other three sites presented lower risks (75, 29, and 18 % for Malta, Menashe, and Serchio, respectively).
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For further information contact us at helpdesk@openaire.euapps Other research product2019 English EC | GLOBAQUAEC| GLOBAQUAAuthors: Diamantini, Elena; Mallucci, Stefano; Bellin, Alberto;Diamantini, Elena; Mallucci, Stefano; Bellin, Alberto;Waters released from wastewater treatment plants (WWTPs) represent a relevant source of pharmaceuticals and personal care products to the aquatic environment, since many of them are not effectively removed by the treatment systems. The consumption of these products increased in the last decades and concerns have consequently risen about their possible adverse effects on the freshwater ecosystem. In this study, we present a simple, yet effective, analytical model of transport of contaminants released in surface waters by WWTPs. Transport of dissolved species is modeled by solving the advection dispersion reaction equation (ADRE) along the river network by using a Lagrangian approach. We applied this model to concentration data of five pharmaceuticals, diclofenac, ketoprofen, clarithromycin, sulfamethoxazole, and irbesartan, collected during two field campaigns, conducted in February and July 2015 in the Adige River, northeastern Italy. The model showed a good agreement with measurements and the successive application at the monthly timescale highlighted significant variations of the load due to the interplay between streamflow seasonality and variation of the anthropogenic pressure, chiefly due to the variability of touristic fluxes. Since the data required by the model are widely available, our model is suitable for large-scale applications.
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apps Other research product2018 English EC | ECLISE, EC | HELIXEC| ECLISE ,EC| HELIXAuthors: Papadimitriou, Lamprini V.; Koutroulis, Aristeidis G.; Grillakis, Manolis G.; Tsanis, Ioannis K.;Papadimitriou, Lamprini V.; Koutroulis, Aristeidis G.; Grillakis, Manolis G.; Tsanis, Ioannis K.;Global climate model (GCM) outputs feature systematic biases that render them unsuitable for direct use by impact models, especially for hydrological studies. To deal with this issue, many bias correction techniques have been developed to adjust the modelled variables against observations, focusing mainly on precipitation and temperature. However, most state-of-the-art hydrological models require more forcing variables, in addition to precipitation and temperature, such as radiation, humidity, air pressure, and wind speed. The biases in these additional variables can hinder hydrological simulations, but the effect of the bias of each variable is unexplored. Here we examine the effect of GCM biases on historical runoff simulations for each forcing variable individually, using the JULES land surface model set up at the global scale. Based on the quantified effect, we assess which variables should be included in bias correction procedures. To this end, a partial correction bias assessment experiment is conducted, to test the effect of the biases of six climate variables from a set of three GCMs. The effect of the bias of each climate variable individually is quantified by comparing the changes in simulated runoff that correspond to the bias of each tested variable. A methodology for the classification of the effect of biases in four effect categories (ECs), based on the magnitude and sensitivity of runoff changes, is developed and applied. Our results show that, while globally the largest changes in modelled runoff are caused by precipitation and temperature biases, there are regions where runoff is substantially affected by and/or more sensitive to radiation and humidity. Global maps of bias ECs reveal the regions mostly affected by the bias of each variable. Based on our findings, for global-scale applications, bias correction of radiation and humidity, in addition to that of precipitation and temperature, is advised. Finer spatial-scale information is also provided, to suggest bias correction of variables beyond precipitation and temperature for regional studies.
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For further information contact us at helpdesk@openaire.euapps Other research product2018 English EC | SWITCH-ONEC| SWITCH-ONPugliese, Alessio; Persiano, Simone; Bagli, Stefano; Mazzoli, Paolo; Parajka, Juraj; Arheimer, Berit; Capell, René; Montanari, Alberto; Blöschl, Günter; Castellarin, Attilio;Our study develops and tests a geostatistical technique for locally enhancing macro-scale rainfall–runoff simulations on the basis of observed streamflow data that were not used in calibration. We consider Tyrol (Austria and Italy) and two different types of daily streamflow data: macro-scale rainfall–runoff simulations at 11 prediction nodes and observations at 46 gauged catchments. The technique consists of three main steps: (1) period-of-record flow–duration curves (FDCs) are geostatistically predicted at target ungauged basins, for which macro-scale model runs are available; (2) residuals between geostatistically predicted FDCs and FDCs constructed from simulated streamflow series are computed; (3) the relationship between duration and residuals is used for enhancing simulated time series at target basins. We apply the technique in cross-validation to 11 gauged catchments, for which simulated and observed streamflow series are available over the period 1980–2010. Our results show that (1) the procedure can significantly enhance macro-scale simulations (regional LNSE increases from nearly zero to ≈0.7) and (2) improvements are significant for low gauging network densities (i.e. 1 gauge per 2000 km2).
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For further information contact us at helpdesk@openaire.euapps Other research product2019 English EC | ECOADAPTEC| ECOADAPTAuthors: Fernández, Alfonso; Muñoz, Ariel; González-Reyes, Álvaro; Aguilera-Betti, Isabella; +8 AuthorsFernández, Alfonso; Muñoz, Ariel; González-Reyes, Álvaro; Aguilera-Betti, Isabella; Toledo, Isadora; Puchi, Paulina; Sauchyn, David; Crespo, Sebastián; Frene, Cristian; Mundo, Ignacio; González, Mauro; Vignola, Raffaele;Streamflow in south-central Chile (SCC, ∼ 37–42∘ S) is vital for agriculture, forestry production, hydroelectricity, and human consumption. Recent drought episodes have generated hydrological deficits with damaging effects on these activities. This region is projected to undergo major reductions in water availability, concomitant with projected increases in water demand. However, the lack of long-term records hampers the development of accurate estimations of natural variability and trends. In order to provide more information on long-term streamflow variability and trends in SCC, here we report findings of an analysis of instrumental records and a tree-ring reconstruction of the summer streamflow of the Río Imperial (∼ 37∘ 40′ S–38∘ 50′ S). This is the first reconstruction in Chile targeted at this season. Results from the instrumental streamflow record (∼ 1940 onwards) indicated that the hydrological regime is fundamentally pluvial with a small snowmelt contribution during spring, and evidenced a decreasing trend, both for the summer and the full annual record. The reconstruction showed that streamflow below the average characterized the post-1980 period, with more frequent, but not more intense, drought episodes. We additionally found that the recent positive phase of the Southern Annular Mode has significantly influenced streamflow. These findings agree with previous studies, suggesting a robust regional signal and a shift to a new hydrological scenario. In this paper, we also discuss implications of these results for water managers and stakeholders; we provide rationale and examples that support the need for the incorporation of tree-ring reconstructions into water resources management.
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For further information contact us at helpdesk@openaire.euapps Other research product2019 English EC | EARTH2OBSERVEEC| EARTH2OBSERVEAuthors: Bhuiyan, Md Abul Ehsan; Nikolopoulos, Efthymios I.; Anagnostou, Emmanouil N.; Quintana-Seguí, Pere; +1 AuthorsBhuiyan, Md Abul Ehsan; Nikolopoulos, Efthymios I.; Anagnostou, Emmanouil N.; Quintana-Seguí, Pere; Barella-Ortiz, Anaïs;This study investigates the use of a nonparametric, tree-based model, quantile regression forests (QRF), for combining multiple global precipitation datasets and characterizing the uncertainty of the combined product. We used the Iberian Peninsula as the study area, with a study period spanning 11 years (2000–2010). Inputs to the QRF model included three satellite precipitation products, CMORPH, PERSIANN, and 3B42 (V7); an atmospheric reanalysis precipitation and air temperature dataset; satellite-derived near-surface daily soil moisture data; and a terrain elevation dataset. We calibrated the QRF model for two seasons and two terrain elevation categories and used it to generate ensemble for these conditions. Evaluation of the combined product was based on a high-resolution, ground-reference precipitation dataset (SAFRAN) available at 5 km 1 h−1 resolution. Furthermore, to evaluate relative improvements and the overall impact of the combined product in hydrological response, we used the generated ensemble to force a distributed hydrological model (the SURFEX land surface model and the RAPID river routing scheme) and compared its streamflow simulation results with the corresponding simulations from the individual global precipitation and reference datasets. We concluded that the proposed technique could generate realizations that successfully encapsulate the reference precipitation and provide significant improvement in streamflow simulations, with reduction in systematic and random error on the order of 20–99 and 44–88 %, respectively, when considering the ensemble mean.
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For further information contact us at helpdesk@openaire.euapps Other research product2019 English EC | SOILTRECEC| SOILTRECAndrianaki, Maria; Shrestha, Juna; Kobierska, Florian; Nikolaidis, Nikolaos P.; Bernasconi, Stefano M.;In this study, we investigated the application and the transferability of the Soil Water and Assessment Tool (SWAT) in a partly glacierized Alpine catchment characterized by extreme climatic conditions and steep terrain. The model was initially calibrated for the 10 km2 watershed of the Damma glacier Critical Zone Observatory (CZO) in central Switzerland using monitoring data for the period of 2009–2011 and then was evaluated for 2012–2013 in the same area. Model performance was found to be satisfactory against both the Nash–Sutcliffe criterion (NS) and a benchmark efficiency (BE). The transferability of the model was assessed by using the parameters calibrated on the small watershed and applying the model to the approximately 100 km2 catchment that drains into the hydropower reservoir of the Göscheneralpsee and includes the Damma glacier CZO. Model results were compared to the reservoir inflow data from 1997 to 2010 and it was found that the model predicted successfully snowmelt timing and autumn recession but could not accurately capture the peak flow for certain years. Runoff was slightly overestimated from late May to June, when it is dominated by snowmelt. Finally, we investigated the response of the greater catchment to climate change using three different climate change scenarios, and the results were compared to those of a previous study, where two different hydrological models, PREVAH and ALPINE3D, were used. The methodology presented here, where SWAT is calibrated for a small watershed and then applied for a bigger area with similar climatic conditions and geographical characteristics, could work even under extreme conditions like ours. However, greater attention should be given to the differences between glacier melt and snowmelt dynamics. In conclusion, this assessment test on the transferability of SWAT on different scales gave valuable information about the strengths and weaknesses of the model when it was applied under conditions different to those under which it was calibrated.
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For further information contact us at helpdesk@openaire.euapps Other research product2018 English EC | CLIMBEC| CLIMBAuthors: Mascaro, G.; Piras, M.; Deidda, R.; Vivoni, E. R.;Mascaro, G.; Piras, M.; Deidda, R.; Vivoni, E. R.;The water resources and hydrologic extremes in Mediterranean basins are heavily influenced by climate variability. Modeling these watersheds is difficult due to the complex nature of the hydrologic response as well as the sparseness of hydrometeorological observations. In this work, we present a strategy to calibrate a distributed hydrologic model, known as TIN-based Real-time Integrated Basin Simulator (tRIBS), in the Rio Mannu basin (RMB), a medium-sized watershed (472.5 km2) located in an agricultural area in Sardinia, Italy. In the RMB, precipitation, streamflow and meteorological data were collected within different historical periods and at diverse temporal resolutions. We designed two statistical tools for downscaling precipitation and potential evapotranspiration data to create the hourly, high-resolution forcing for the hydrologic model from daily records. Despite the presence of several sources of uncertainty in the observations and model parameterization, the use of the disaggregated forcing led to good calibration and validation performances for the tRIBS model, when daily discharge observations were available. The methodology proposed here can be also used to disaggregate outputs of climate models and conduct high-resolution hydrologic simulations with the goal of quantifying the impacts of climate change on water resources and the frequency of hydrologic extremes within medium-sized basins.
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For further information contact us at helpdesk@openaire.euapps Other research product2019 English EC | MARSOLEC| MARSOLRodríguez-Escales, Paula; Canelles, Arnau; Sanchez-Vila, Xavier; Folch, Albert; Kurtzman, Daniel; Rossetto, Rudy; Fernández-Escalante, Enrique; Lobo-Ferreira, João-Paulo; Sapiano, Manuel; San-Sebastián, Jon; Schüth, Christoph;Managed aquifer recharge (MAR) can be affected by many risks. Those risks are related to different technical and non-technical aspects of recharge, like water availability, water quality, legislation, social issues, etc. Many other works have acknowledged risks of this nature theoretically; however, their quantification and definition has not been developed. In this study, the risk definition and quantification has been performed by means of “fault trees” and probabilistic risk assessment (PRA). We defined a fault tree with 65 basic events applicable to the operation phase. After that, we have applied this methodology to six different managed aquifer recharge sites located in the Mediterranean Basin (Portugal, Spain, Italy, Malta, and Israel). The probabilities of the basic events were defined by expert criteria, based on the knowledge of the different managers of the facilities. From that, we conclude that in all sites, the perception of the expert criteria of the non-technical aspects were as much or even more important than the technical aspects. Regarding the risk results, we observe that the total risk in three of the six sites was equal to or above 0.90. That would mean that the MAR facilities have a risk of failure equal to or higher than 90 % in the period of 2–6 years. The other three sites presented lower risks (75, 29, and 18 % for Malta, Menashe, and Serchio, respectively).
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For further information contact us at helpdesk@openaire.euapps Other research product2019 English EC | GLOBAQUAEC| GLOBAQUAAuthors: Diamantini, Elena; Mallucci, Stefano; Bellin, Alberto;Diamantini, Elena; Mallucci, Stefano; Bellin, Alberto;Waters released from wastewater treatment plants (WWTPs) represent a relevant source of pharmaceuticals and personal care products to the aquatic environment, since many of them are not effectively removed by the treatment systems. The consumption of these products increased in the last decades and concerns have consequently risen about their possible adverse effects on the freshwater ecosystem. In this study, we present a simple, yet effective, analytical model of transport of contaminants released in surface waters by WWTPs. Transport of dissolved species is modeled by solving the advection dispersion reaction equation (ADRE) along the river network by using a Lagrangian approach. We applied this model to concentration data of five pharmaceuticals, diclofenac, ketoprofen, clarithromycin, sulfamethoxazole, and irbesartan, collected during two field campaigns, conducted in February and July 2015 in the Adige River, northeastern Italy. The model showed a good agreement with measurements and the successive application at the monthly timescale highlighted significant variations of the load due to the interplay between streamflow seasonality and variation of the anthropogenic pressure, chiefly due to the variability of touristic fluxes. Since the data required by the model are widely available, our model is suitable for large-scale applications.
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