research data . Dataset . 2021

Porous shape-persistent rylene imine cages with tunable optoelectronic properties and delayed fluorescence

Hsin-Hua Huang; Song, Kyung Seob; Prescimone, Alessandro; Aster, Alexander; Cohen, Gabriel; Mannancherry, Rajesh; Vauthey, Eric; Coskun, Ali; Tom´Aˇs ˇSolomek;
Open Access
  • Published: 09 Mar 2021
  • Publisher: Zenodo
A simultaneous combination of porosity and tunable optoelectronic properties, common in covalent organic frameworks, is rare in shape-persistent organic cages. Yet, organic cages offer important molecular advantages such as solubility and modularity. Herein, we report the synthesis of a series of chiral imine organic cages with three built-in rylene units by means of dynamic imine chemistry and we investigate their textural and optoelectronic properties. Thereby we demonstrate that the synthesized rylene cages can be reversibly reduced at accessible potentials, absorb from UV up to green light, are porous, and preferentially adsorb CO2 over N2 and CH4 with a goo...
free text keywords: cage molecule, porous material
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