Complexes as New Highly Efficient and
Air-Stable Catalysts for the
Cycloisomerization of Enynes
- Publisher: Figshare
Biophysics | Biochemistry | Medicine | Cell Biology | Sociology | 39999 Chemical Sciences not elsewhere classified | enyne | efficient | cycloisomerization | phosphine | new | moiety | enynes cycloisomerizations | complex | catalyst | phosphine | bis | synthesis | catalysi | bi | complexe | counteranion
A study concerning the synthesis of new phosphine gold(I) complexes using the bis(trifluoromethanesulfonyl)imidate moiety as a weakly
coordinating counteranion is described. These new air-stable complexes are more convenient to prepare, store, and handle and are exceedingly
active for the catalysis of a wide range of enynes cycloisomerizations.