Phosphine Gold(I) Bis-(trifluoromethanesulfonyl)imidate Complexes as New Highly Efficient and Air-Stable Catalysts for the Cycloisomerization of Enynes

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Mézailles, Nicolas ; Ricard, Louis ; Gagosz, Fabien (2005)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ol0515917.s002
  • Subject: Biophysics | Biochemistry | Medicine | Cell Biology | Sociology | 39999 Chemical Sciences not elsewhere classified | enyne | efficient | cycloisomerization | phosphine | new | moiety | enynes cycloisomerizations | complex | catalyst | phosphine | bis | synthesis | catalysi | bi | complexe | counteranion

A study concerning the synthesis of new phosphine gold(I) complexes using the bis(trifluoromethanesulfonyl)imidate moiety as a weakly coordinating counteranion is described. These new air-stable complexes are more convenient to prepare, store, and handle and are exceedingly active for the catalysis of a wide range of enynes cycloisomerizations.
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