Neutral Aminyl Radicals Derived from Azoimidazolium Dyes

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Eymann, Léonard Y. M.; Tskhovrebov, Alexander G.; Sienkiewicz, Andrzej; Bila, José L.; Živković, Ivica; Rønnow, Henrik M.; Wodrich, Matthew D.; Vannay, Laurent; Corminboeuf, Clémence; Pattison, Philip; Solari, Euro; Scopelliti, Rosario; Severin, Kay;
(2016)

The synthesis and characterization of a new class of neutral aminyl radicals is reported. Monoradicals were obtained by reduction of azoimidazolium dyes with potassium. Structural, spectroscopic, and computational data suggest that the spin density is center... View more
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