Synthesis, Structure, and Luminescence of Di- and Trinuclear Palladium/Gold and Platinum/Gold Complexes with (2,7-Di-tert-butylfluoren-9-ylidene)methanedithiolate,1

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Vicente, José; González-Herrero, Pablo; Pérez-Cadenas, María; Jones, Peter G.; Bautista, Delia;
(2007)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ic070164h.s006, doi: 10.1021/ic070164h.s004
  • Subject: diimine | Pt | Pd complexes 2 | tert | Sociology | Å. | Medicine | charge transfer | molar | Space Science | 77 K | 4 b | Biochemistry | 5 b | HOMO | MLCT triplet state | Biophysics | ratio
    • FOR: 80699 Information Systems not elsewhere classified | 29999 Physical Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

Acetone solutions of [Au(OClO<sub>3</sub>)(PCy<sub>3</sub>)] react with complexes [M{S<sub>2</sub>C=(<i>t</i>-Bu-fy)}<sub>2</sub>]<sup>2-</sup> [<i>t</i>-Bu-fy = 2,7-di-<i>tert</i>-butylfluoren-9-ylidene; M = Pd (<b>2a</b>), Pt (<b>2b</b>)] or [M{S<sub>2</sub>C=(<i>t</i... View more
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