Dihydrogen and Acetylene Activation by a Gold(I)/Platinum(0) Transition Metal Only Frustrated Lewis Pair

Campos, Jesús;
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/jacs.7b00491.s002, doi: 10.1021/jacs.7b00491.s003, doi: 10.1021/jacs.7b00491.s004
  • Subject: terphenyl phosphine ligands | Frustrated Lewis Pair | P t Bu 3 | capacity | Lewis adducts | Evolutionary Biology | acetylene molecules | Lewis acidic | transition metal centers | Biochemistry | complex | Lewis pair | Cancer | group FLP systems | HC | Acetylene Activation
    • FOR: 59999 Environmental Sciences not elsewhere classified | 29999 Physical Sciences not elsewhere classified | 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

The first example of a frustrated Lewis pair (FLP) solely constructed around transition metal centers is described in this work. We have focused on the established capacity of Au­(I) and Pt(0) complexes to act as Lewis acidic and basic fragments, respectivel... View more
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