Copper(I)−α-Ketocarboxylate Complexes:  Characterization and O2 Reactions That Yield Copper−Oxygen Intermediates Capable of Hydroxylating Arenes

Hong, Sungjun; Huber, Stefan M.; Gagliardi, Laura; Cramer, Christopher C.; Tolman, William B.;

A series of copper(I)−α-ketocarboxylate complexes have been prepared and shown to exhibit variable coordination modes of the α-ketocarboxylate ligand. Reaction with O<sub>2</sub> induces decarboxylation of this ligand, and the derived copper−oxygen intermediate(s) has b... View more
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