Synthesis of Kinetically Stabilized 1,2-Dihydrodisilenes

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Agou, Tomohiro; Sugiyama, Yusuke; Sasamori, Takahiro; Sakai, Heisuke; Furukawa, Yukio; Takagi, Nozomi; Guo, Jing-Dong; Nagase, Shigeru; Hashizume, Daisuke; Tokitoh, Norihiro;
(2012)

Kinetically stabilized 1,2-dihydrodisilenes were successfully synthesized and isolated by the introduction of sterically protecting bulky aryl groups. These 1,2-dihydrodisilenes exhibit distinct SiSi double-bond character in both solution and the solid stat... View more
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