Amide−Silyl Ligand Exchanges and Equilibria among Group 4 Amide and Silyl Complexes

Dataset UNKNOWN
Cai, Hu; Yu, Xianghua; Chen, Shujian; Qiu, He; Guzei, Ilia A.; Xue, Zi-Ling;
(2007)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ic7010293.s006, doi: 10.1021/ic7010293.s007, doi: 10.1021/ic7010293.s008
  • Subject: 2 N | Plant Biology | silyl anion 2 | Pharmacology | Biophysics | Immunology | equilibria | SiBu t Ph 2 | Neuroscience | Physiology | Medicine | Computational Biology | Cell Biology | THF | 1 b | 3 b | 4 b | Biochemistry | Zr | 6 b | Cancer | 9 b | 5 Li 2 | Group 4 Amide | Hf
    • FOR: 39999 Chemical Sciences not elsewhere classified

M(NMe<sub>2</sub>)<sub>4</sub> (M = Zr, <b>1a</b>; Hf, <b>1b</b>) and the silyl anion (SiBu<sup>t</sup>Ph<sub>2</sub>)<sup>-</sup> (<b>2</b>) in Li(THF)<sub>2</sub>SiBu<sup>t</sup>Ph<sub>2</sub> (<b>2</b>-Li) were found to undergo a ligand exchange to give [M(NMe<sub... View more
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