An Unusual Three-Dimensional Water Cluster in Metal−Organic Frameworks Based on ZnX2 (X = ClO4, BF4) and an Azo-Functional Ligand

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Jin, Chuan-Ming; Zhu, Zhu; Chen, Zhan-Fen; Hu, Yan-Jun; Meng, Xiang-Gao;
(2010)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/cg100226u.s003, doi: 10.1021/cg100226u.s004
  • Subject: Molecular Biology | 3 D water clathrate network | BF | Medicine | Space Science | Ecology | framework | water network | Cancer | H 2O | ZnX 2
    • FOR: 59999 Environmental Sciences not elsewhere classified | 20199 Astronomical and Space Sciences not elsewhere classified | 110309 Infectious Diseases | 69999 Biological Sciences not elsewhere classified

A highly symmetrical three-dimensional (3D) water network containing cage-shaped tetradecameric water cluster units (H<sub>2</sub>O)<sub>14</sub> is observed in the crystalline 3D metal−organic framework materials <b>1</b> and <b>2</b>. This is a rare demonstration of a... View more
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