Thermal and Photochemical Cleavage of SiSi Double Bond in Tetrasila-1,3-diene

Dataset UNKNOWN
Uchiyama, Kei; Nagendran, Selvarajan; Ishida, Shintaro; Iwamoto, Takeaki; Kira, Mitsuo;
(2007)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ja0741473.s002, doi: 10.1021/ja0741473.s003
  • Subject: anticlinal conformation | Inorganic Chemistry | synclinal conformation | novel cyclotrisilene 4 | Neuroscience | bond dissociation | Physiology | silylene 2 | Computational Biology | Photochemical Cleavage | Cell Biology | 390 nm | Si | tetrasila | intramolecular silylene insertion | Biophysics | disilenylsilylene 8
    • FOR: 80699 Information Systems not elsewhere classified | 59999 Environmental Sciences not elsewhere classified | 29999 Physical Sciences not elsewhere classified | 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

A novel stable tetrasila-1,3-diene <b>3</b> was synthesized by the reduction with sodium of the corresponding 1,2,2-tribromodisilane. X-ray analysis shows that the tetrasila-1,3-diene skeleton of <b>3</b> is highly twisted but adopts an <i>anticlinal</i> conformation in... View more
Share - Bookmark

  • Download from
    figshare via figshare (Dataset, 2007)
  • Cite this research data