Palladium-Catalyzed, Site-Selective Direct Allylation of Aryl C–H Bonds by Silver-Mediated C–H Activation: A Synthetic and Mechanistic Investigation

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Lee, Sarah Yunmi; Hartwig, John F.;
(2016)

We describe a method for the site-selective construction of a C­(aryl)–C­(sp<sup>3</sup>) bond by the palladium-catalyzed direct allylation of arenes with allylic pivalates in the presence of AgOPiv to afford the linear (<i>E</i>)-allylated arene with excell... View more
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