Generation, Direct Observation, and Kinetics of Triplet 9-(1,1,4,4,5,5,8,8- Octamethyl-1,2,3,4,5,6,7,8-octahydro- anthryl)phenylcarbene

Iikubo, Takashi; Hirai, Katsuyuki; Tomioka, Hideo;
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ol026119p.s001, doi: 10.1021/ol026119p.s002
  • Subject: Molecular Biology | triplet carbene | carbene center | Direct Observation | Neuroscience | Biochemistry | Plant Biology | title triplet carbene | Science Policy | Computational Biology
    • FOR: 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

Reactivities of the title triplet carbene were compared with those of the “untied” counterpart, [2,4,6-tris(<i>tert</i>)butylphenyl](phenyl)carbene. An appreciable increase in the stability of triplet carbene is noted by tuning the distance between the <i>o</i>-hydro... View more
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