Unravelling the Mechanism of Basic Aqueous Methanol Dehydrogenation Catalyzed by Ru–PNP Pincer Complexes

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Alberico, Elisabetta; Lennox, Alastair J. J.; Vogt, Lydia K.; Jiao, Haijun; Baumann, Wolfgang; Drexler, Hans-Joachim; Nielsen, Martin; Spannenberg, Anke; Checinski, Marek P.; Junge, Henrik; Beller, Matthias;
(2016)

Ruthenium PNP complex <b>1a</b> (RuH­(CO)­Cl­(HN­(C<sub>2</sub>H<sub>4</sub>P<i>i</i>-Pr<sub>2</sub>)<sub>2</sub>)) represents a state-of-the-art catalyst for low-temperature (<100 °C) aqueous methanol dehydrogenation to H<sub>2</sub> and CO<sub>2</sub>. Herein, w... View more
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