Multinuclear Calixarene Synthons with Covalently Linked Aryl-Palladium(II) Complexes

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Kleij, Arjan W.; Souto, Beatriz; Pastor, César J.; Prados, Pilar; Mendoza, Javier de;
(2004)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/jo0494782.s002, doi: 10.1021/jo0494782.s001
  • Subject: dba | metal sites | Multinuclear Calixarene Synthons | Medicine | Ecology | Pd 2 | NMR | Cell Biology | Genetics | Biochemistry | complex | precursor | Cancer | metallacalixarene building blocks | L n | tmeda | Biophysics | oxidative addition
    • FOR: 59999 Environmental Sciences not elsewhere classified | 19999 Mathematical Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

New synthetic procedures have been developed for potentially useful metallacalixarene building blocks. The metal sites were covalently connected to calix[<i>n</i>]arenes (<i>n</i> = 4, 6) by oxidative addition of 4-iodobenzyl precursors to either Pd(PPh<sub>3</sub... View more
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