Stereoselective Synthesis of 1-Nitrobicyclo[3.1.0]hexanes and Fused Isoxazoline-N-oxides from Primary Nitro Compounds

Kamimura, Akio; Takeuchi, Ryota; Ikeda, Kosuke; Moriyama, Takaaki; Sumimoto, Michinori;

The one-step preparation of 1-nitrobicyclo[3.1.0]­hexane and bicycloisoxazoline-<i>N</i>-oxide was readily achieved from conjugate adducts of nitro alkenes and allylmalonates by treatment with Ag<sub>2</sub>O and iodine under basic conditions. We observed th... View more
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