Bis(imino)pyridine Ligand Deprotonation Promoted by a Transient Iron Amide

Dataset UNKNOWN
Bouwkamp, Marco W.; Lobkovsky, Emil; Chirik, Paul J.;
(2006)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ic051839o.s002, doi: 10.1021/ic051839o.s003, doi: 10.1021/ic051839o.s004
  • Subject: Molecular Biology | Biotechnology | THF solution | chelate methyl groups | i Pr PDEA | bi | iron dialkyl | Evolutionary Biology | Pharmacology | implicating formation | amide bases | Biophysics | 2 equiv | amine ligand | KN | Neuroscience | Developmental Biology | Physiology | iron amide | 2 C 5 H 3 N | Cell Biology | LiNMe 2 | NC | Transient Iron Amide Addition | i Pr PDI | Biochemistry | Cancer
    • FOR: 59999 Environmental Sciences not elsewhere classified | 19999 Mathematical Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified
    acm: TheoryofComputation_ANALYSISOFALGORITHMSANDPROBLEMCOMPLEXITY

Addition of 2 equiv of LiNMe<sub>2</sub> to the bis(imino)pyridine ferrous dichloride, (<i><sup>i</sup></i><sup>Pr</sup>PDI)FeCl<sub>2</sub> (<i><sup>i</sup></i><sup>Pr</sup>PDI = (2,6-<i><sup>i</sup></i><sup></sup>Pr<sub>2</sub>−C<sub>6</sub>H<sub>3</sub>NCMe)<sub>... View more
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