Base-Promoted Tautomerization of Imidazole Ligands to N-Heterocyclic Carbenes and Subsequent Transmetalation Reaction

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Ruiz, Javier; Perandones, Bernabé F.;
(2007)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ja073144n.s003, doi: 10.1021/ja073144n.s004, doi: 10.1021/ja073144n.s002
  • Subject: Molecular Biology | sequential transmetalation reaction | proceed | Subsequent Transmetalation ReactionImidazole complexes | Neuroscience | derivative | isolable heterometallic | carbene | manganese | acid | Ecology | Genetics | Evolutionary Biology | species | Biochemistry | Tautomerization | Imidazole Ligands
    • FOR: 80699 Information Systems not elsewhere classified | 110309 Infectious Diseases | 39999 Chemical Sciences not elsewhere classified

Imidazole complexes of manganese(I) are transformed into their corresponding N-heterocyclic carbene derivatives by means of acid−base treatments; the subsequent sequential transmetalation reaction of the carbene to gold(I) proceeds through isolable heterometallic interm... View more
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