Si–H Activation in an Iridium Nitrido ComplexA Mechanistic and Theoretical Study

Sieh, Daniel; Burger, Peter;

Si–H activation in triethyl- and triarylsilanes by a square-planar pyridine-diimine iridium complex with a terminal nitrido unit leads to the corresponding silyl amido complexes, which were unambiguously characterized by X-ray crystallography. Based on detai... View more
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