Hybrid Triazine-Boron Two-Dimensional Covalent Organic Frameworks: Synthesis, Characterization, and DFT Approach to Layer Interaction Energies

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Gontarczyk, Krzysztof; Bury, Wojciech; Serwatowski, Janusz; Wieciński, Piotr; Woźniak, Krzysztof; Durka, Krzysztof; Luliński, Sergiusz;
(2017)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/acsami.7b09061.s003, doi: 10.1021/acsami.7b09061.s002
  • Subject: S BET | PXRD studies | Biotechnology | triboronic acid | sorption properties | decomposition temperatures | electron density surfaces | 2 D honeycomb-type lattices | formation | IR analysis | Ecology | Crystal 09 package | ellipsoidal clusters | CTF | 77.2 K | Biophysics | dehydrative condensation reactions | procrystal electron density approach | DFT Approach | rodlike particles | work function values | STP | boroxine rings | 2 D COF | DFT modeling | Biochemistry | nitrogen uptake | COFs exhibit | layer interaction energies | benzene rings | boroxine-triazine material | NMR studies | Hybrid Triazine-Boron Two-Dimensional Covalent Organic Frameworks | water-decomposed samples
    • FOR: 59999 Environmental Sciences not elsewhere classified | 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

The conversion of 2,4,6-tris­(4′-bromophenyl)-1,3,5-triazine to the respective triboronic acid was successfully accomplished by a simple triple Br/Li exchange followed by boronation. Further dehydrative condensation reactions with 2,3,6,7,10,11-hexahydroxytr... View more
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