Electron-Transfer-Catalyzed Rearrangement of Unsymmetrically Substituted Diiron Dithiolate Complexes Related to the Active Site of the [FeFe]-Hydrogenases

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Ezzaher, Salah; Capon, Jean-François; Gloaguen, Frédéric; Pétillon, François Y.; Schollhammer, Philippe; Talarmin, Jean;
(2007)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ic701327w.s007, doi: 10.1021/ic701327w.s009, doi: 10.1021/ic701327w.s008, doi: 10.1021/ic701327w.s010
  • Subject: Ph 2 PCH 2 CH 2 PPh 2 | i Pr | IR | CO | Ecology | NMR | THF | CH 2 CH 2 OCH 3 | ETC | PF | Biochemistry | Pharmacology | CH 2 C 6 H 5 | SCH | Unsymmetrically Substituted Diiron Dithiolate Complexes Related | dppe ligand bridges | Biophysics | Fe 2
    • FOR: 59999 Environmental Sciences not elsewhere classified | 29999 Physical Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

Novel asymmetrically substituted azadithiolate compounds [Fe<sub>2</sub>(CO)<sub>4</sub>(κ<sup>2</sup>-dppe){μ-SCH<sub>2</sub>N(R)CH<sub>2</sub>S}] (R = <i><sup>i</sup></i><sup></sup>Pr, <b>1a</b>; CH<sub>2</sub>CH<sub>2</sub>OCH<sub>3</sub>, <b>1b</b>; CH<sub>2</sub... View more
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