Toward Asymmetric Aldol-Tishchenko Reactions with Enolizable Aldehydes: Access to Defined Configured Stereotriads, Tetrads, and Stereopentads

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Rohr, Kerstin; Herre, Robert; Mahrwald, Rainer;
(2009)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/jo9003635.s003, doi: 10.1021/jo9003635.s002, doi: 10.1021/jo9003635.s001
  • Subject: configurative architecture | Developmental Biology | Sociology | Medicine | rate constants | configured stereotriads | Computational Biology | Evolutionary Biology | enolizable aldehydes | transition state models | considerations offer | Asymmetric | Biophysics | Immunology | Defined Configured Stereotriads | Different configurative outcomes
    • FOR: 29999 Physical Sciences not elsewhere classified | 110309 Infectious Diseases | 19999 Mathematical Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

Asymmetric aldol-Tishchenko reactions of enolizable aldehydes and ketones in the presence of chiral BINOLTi(O<i>t</i>Bu)<sub>2</sub>/cinchona alkaloids complexes are described. Different configurative outcomes of these reactions depend on an equilibration through a retr... View more
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