Construction of Two 3D Homochiral Frameworks with 1D Chiral Pores via Chiral Recognition

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Li, Huan-Yong; Jiang, Long; Xiang, Hua; Makal, Trevor A.; Zhou, Hong-Cai; Lu, Tong-Bu;
(2011)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ic200264s.s003, doi: 10.1021/ic200264s.s002
  • Subject: Chiral RecognitionThe reactions | pore | macrocyclic | helical | Space Science | complex | enantiomer | 1 D Chiral Pores | Construction | penicillaminedisulfide anion | Science Policy | Immunology | 3 D Homochiral Frameworks | pend | hexamethyl | surface | racemic penicillamine | ClO | Microbiology | Medicine | right | Computational Biology | homochiral | framework | 1 D | Biochemistry | Ni
    • FOR: 59999 Environmental Sciences not elsewhere classified | 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

The reactions of a pair of enantiomers of macrocyclic nickel(II) complexes with racemic penicillamine generated two 3D hydrogen-bonded homochiral frameworks of {[Ni(<i>f</i>-(<i>SS</i>)-L)]<sub>2</sub>(<i>l</i>-pends)(ClO<sub>4</sub>)<sub>2</sub>}<sub><i>n</i></sub> (Λ-... View more
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