Electrochiroptical Response of 2,2‘-(2,2-Diarylethenyl)binaphthyl-Type Electron Donors That Undergo Reversible C−C Bond Formation/Breaking upon Two-Electron Transfer

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Higuchi, Hiroki; Ohta, Eisuke; Kawai, Hidetoshi; Fujiwara, Kenshu; Tsuji, Takashi; Suzuki, Takanori;
(2003)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/jo0345289.s003, doi: 10.1021/jo0345289.s001, doi: 10.1021/jo0345289.s002
  • Subject: Molecular Biology | electrochiroptical system | electron donor | Electrochiroptical Response | Marine Biology | Genetics | diolefin 1 | Pharmacology | CD spectra | electrochemical transformation | Biophysics | Immunology | UV | Developmental Biology | Microbiology | bond | dication rac | dication salt | electrochromic system | electrochemical bistability | binaphthylic diolefin rac | Biochemistry
    • FOR: 80699 Information Systems not elsewhere classified | 29999 Physical Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

2,2‘-[2,2-Bis(4-dimethylaminophenyl)ethenyl]biphenyl (<b>1</b>) is a strong electron donor that undergoes oxidative C−C bond formation to give a stable dication <i>rac</i>-<b>2</b><sup>2+</sup>, the 9,10-dihydrophenanthrene derivative substituted with two bis(4-di... View more
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