Switchable Palladium-Catalyst Reaction of Bromomethyl Sulfoxides, CO, and N‑Nucleophiles: Aminocarbonylation at Csp3 versus Oxidative Carbonylation of Amines

Dataset UNKNOWN
Mollar, Cristian; Arellano, Carmen Ramirez de; Medio-Simón, Mercedes; Asensio, Gregorio;
(2012)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/jo301778n.s001, doi: 10.1021/jo301778n.s002
  • Subject: hydroxy sulfinyl amides | bromomethyl | Biochemistry | amines | carbon monoxide | CO | sulfoxide
    • FOR: 110309 Infectious Diseases | 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

The palladium-catalyzed reaction of α-bromomethyl sulfoxides, carbon monoxide, and N-nucleophiles follows different reaction pathways according to the catalytic system and the reaction conditions. The Pd-xantphos catalyst affords high yields of α-sulfinyl am... View more
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