Enhanced Photosensitive Schottky Diode Behavior of Pyrazine over 2‑Aminopyrimidine Ligand in Copper(II)-Phthalate MOFs: Experimental and Theoretical Rationalization

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Hossain, Anowar; Dey, Arka; Seth, Saikat Kumar; Ray, Partha Pratim; Ballester, Pablo; Pritchard, Robin G.; Ortega-Castro, Joaquín; Frontera, Antonio; Mukhopadhyay, Subrata;
(2018)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/acsomega.8b01111.s003, doi: 10.1021/acsomega.8b01111.s002
  • Subject: Enhanced Photosensitive Schottky Diode Behavior | Biotechnology | pyrazine ligands | photosensitivity | MOF | optoelectronic device applications | C 20 H 18 CuN 2 O 10 | Experimental | Ligand | irradiation | barrier | X-ray single-crystal diffraction | conductivity | 2 show | spectroscopically | C 40 H 34 Cu 2 N 6 O 18 | potentiality | Aminopyrimidine | phthalate ion | Pyrazine | thin-film | framework | 2- aminopyrimidine | diode | investigation | Cancer | light increases | Theoretical Rationalization
    • FOR: 29999 Physical Sciences not elsewhere classified | 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

Two novel Cu­(II)-based metal–organic frameworks [C<sub>40</sub>H<sub>34</sub>Cu<sub>2</sub>N<sub>6</sub>O<sub>18</sub> (<b>1</b>) and C<sub>20</sub>H<sub>18</sub>CuN<sub>2</sub>O<sub>10</sub> (<b>2</b>)] have been synthesized using 2-aminopyrimidine or pyrazine ... View more
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