Facile Ruthenium(IV)-Catalyzed Single and Double Allylation of Indole Compounds using Alcohols as Substrates: Aspects of Ruthenium(IV) Allyl Chemistry

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Gruber, Stefan; Zaitsev, Alexey B.; Wörle, Michael; Pregosin, Paul S.; Veiros, Luis F.;
(2008)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/om800295z.s003, doi: 10.1021/om800295z.s002
  • Subject: Stoichiometric reactions | pentadienyl ligands | allyl alcohols | Ru | pentadienyl moiety | Plant Biology | indole compounds | bromo salt 14 | Genetics | Evolutionary Biology | stability difference | Pharmacology | Biophysics | Inorganic Chemistry | CHCH | CH | Developmental Biology | Double Allylation | CN | Computational Biology | allyl source | Cell Biology | DFT | PF | Biochemistry | vinyl epoxides | interligand repulsion | Preliminary experiments
    • FOR: 39999 Chemical Sciences not elsewhere classified

The dicationic Ru(IV) salt [Ru(Cp*)(η<sup>3</sup>-C<sub>3</sub>H<sub>5</sub>)(CH<sub>3</sub>CN)<sub>2</sub>](PF<sub>6</sub>)<sub>2</sub> is shown to be an excellent and rapid catalyst for the C-allylation of indole compounds using <i>allyl alcohols</i> as substrates. Se... View more
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