Formal Homoiodo Allylsilane Annulations: Dual Total Syntheses of (±)-Hirsutene and (±)-Capnellene

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Shen, Shou-Jie; Li, Wei-Dong Z.;
(2013)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/jo4009854.s002, doi: 10.1021/jo4009854.s001
  • Subject: Molecular Biology | hirsutene | Plant Biology | type | approach | Marine Biology | Space Science | Ecology | Dual | Pharmacology | Biophysics | Formal Homoiodo Allylsilane Annulations | synthesis | triquinane sesquiterpenes | bicyclic framework | Cyclic homoiodo allylsilanes | Microbiology | CapnelleneDual | Medicine | elaboration | Eudesmane sesquiterpenoids | bifunctional synthons | capnellene | annulation | Biochemistry | cyclopropanated cyclopentenones | synthese | strategy
    • FOR: 59999 Environmental Sciences not elsewhere classified | 69999 Biological Sciences not elsewhere classified

Dual total syntheses of (±)-hirsutene and (±)-capnellene, two typical linear triquinane sesquiterpenes, were achieved via a formal [3 + 2] annulation strategy, as illustrated schematically. Cyclic homoiodo allylsilanes were employed as key bifunctional synth... View more
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