Euphomilones A and B, ent-Rosane Diterpenoids with 7/5/6 and 5/7/6 Skeletons from Euphorbia milii

Dataset UNKNOWN
Liu, Shao-Nan; Huang, Dane; Morris-Natschke, Susan L.; Ma, Hang; Liu, Zhi-hong; Seeram, Navindra P.; Xu, Jun; Lee, Kuo-Hsiung; Gu, Qiong;
(2016)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/acs.orglett.6b03142.s002, doi: 10.1021/acs.orglett.6b03142.s003
  • Subject: ECD | formation | ligand | Skeleton | euphomianol | Pharmacology | spectroscopic | rosane | ent-Rosane | Euphomilone | IC | Biophysics | Inorganic Chemistry | X-ray diffraction data | Physiology | inhibition | Medicine | ent | analysis | compound | dichroism | receptor | RANKL | Plausible biogenetic pathways | Biochemistry | 12.6 μ M | diterpenoid | activator | factor-kappaB | osteoclast | Euphorbia milii
    • FOR: 59999 Environmental Sciences not elsewhere classified | 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

Three highly modified <i>ent</i>-rosane diterpenoids, euphomilones A (<b>1</b>) and B (<b>2</b>) and euphomianol A (<b>3</b>), were isolated from the aerial parts of <i>Euphorbia milii</i>. The structures were elucidated from physical, spectroscopic, and X-r... View more
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