Four-Coordinate Iron(II) Porphyrinates:  Electronic Configuration Change by Intermolecular Interaction

Hu, Chuanjiang; Noll, Bruce C.; Schulz, Charles E.; Scheidt, W. Robert;
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ic0620182.s002, doi: 10.1021/ic0620182.s003, doi: 10.1021/ic0620182.s001
  • Subject: phase | Biotechnology | Microbiology | Physiology | tetraarylporphyrin species | Medicine | Hematology | porphyrin plane | Biochemistry | Pharmacology | iron atom | susceptibility measurements | Biophysics | Intermolecular InteractionThe syntheses | porphyrin core | m össbauer spectra | Fe
    • FOR: 29999 Physical Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

The syntheses and structures of three four-coordinate iron(II) porphyrinates are reported. The three derivatives are tetraarylporphyrin species, where the aryl is either phenyl, <i>p</i>-methylphenyl, or <i>p</i>-methoxyphenyl. One of these derivatives, that of te... View more
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