Stoichiometric Photoisomerization of Mononuclear Ruthenium(II) Monoaquo Complexes Controlling Redox Properties and Water Oxidation Catalysis

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Yamazaki, Hirosato; Hakamata, Tomoya; Komi, Manabu; Yagi, Masayuki;
(2011)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ja2024228.s002, doi: 10.1021/ja2024228.s003
  • Subject: water oxidation catalysis | aquo | Medicine | Marine Biology | Space Science | ruthenium | Cell Biology | Genetics | photoexcited states | Biochemistry | Water Oxidation CatalysisAlthough | complex | redox reactions | Cancer | Stoichiometric Photoisomerization | Biophysics | water oxidation catalyses
    • FOR: 39999 Chemical Sciences not elsewhere classified

Although various reactions involved in photoexcited states of polypyridyl ruthenium(II) complexes have been extensively studied, photoisomerization of the complexes is very rare. We report the first illustration of stoichiometric photoisomerization of <i>trans</i>-[Ru(t... View more
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