Thermally Programmable Gas Storage and Release in Single Crystals of an Organic van der Waals Host

Dataset UNKNOWN
Enright, Gary D.; Udachin, Konstantin A.; Moudrakovski, Igor L.; Ripmeester, John A.;
(2003)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ja0351701.s002, doi: 10.1021/ja0351701.s001
  • Subject: Molecular Biology | Biotechnology | van der Waals materials | butylcalix | tert | release | crystal | pore system | hyperpolarized xenon | Ecology | Genetics | Evolutionary Biology | zeolite mimics | room temperature access | Single Crystals | Physiology | prospect | Cell Biology | Biochemistry | NMR spectroscopy | guest molecules | density form | Organic van der Waals Host | title material | Thermally Programmable Gas Storage
    • FOR: 110309 Infectious Diseases | 60506 Virology | 39999 Chemical Sciences not elsewhere classified

A single crystal of a low density form of guest-free <i>p</i>-<i>tert</i>-butylcalix[4]arene can take up and release small guest molecules by controlling the temperature and pressure without changing the structure. Using NMR spectroscopy with flowing hyperpolarized xeno... View more
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