Convergent Total Syntheses of the Amaryllidaceae Alkaloids Lycoranine A, Lycoranine B, and 2‑Methoxypratosine

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Kim, Hye Sun; Banwell, Martin G.; Willis, Anthony C.;
(2016)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/jo4006987.s002, doi: 10.1021/jo4006987.s003, doi: 10.1021/jo4006987.s004
  • Subject: Molecular Biology | borolated indole | methoxyindole | Biotechnology | convergent manner | crystal | Convergent | Sociology | alkaloids | Amaryllidaceae Alkaloids Lycoranine | sample | functionalization | analyses | Hartwig | compounds 1 | Ecology | MethoxypratosineThe | Lycoranine B | bromobenzoate | Synthese | Biophysics | synthetically
    • FOR: 39999 Chemical Sciences not elsewhere classified

The title alkaloids, <b>1</b>, <b>2</b>, and <b>3</b> respectively, have been prepared in a convergent manner by two related routes. The superior one involves C–H functionalization of the relevant 5-methoxyindole at C-7 using Hartwig’s protocol and thus form... View more
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