Highly Efficient Large Bite Angle Diphosphine Substituted Molybdenum Catalyst for Hydrosilylation

Chakraborty, Subrata; Blacque, Olivier; Fox, Thomas; Berke, Heinz;

Treatment of the complex Mo­(NO)­Cl<sub>3</sub>(NCMe)<sub>2</sub> with the large bite angle diphosphine, 2,2′-bis­(di­phenyl­phos­phino)­diphenylether (DPEphos) afforded the dinuclear species [Mo­(NO)­(P∩P)­Cl<sub>2</sub>]<sub>2</sub>[μCl]<sub>2</sub> (P∩P = DP... View more
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