Design, Synthesis, and Dynamics of a Green Fluorescent Protein Fluorophore Mimic with an Ultrafast Switching Function

Paolino, Marco; Gueye, Moussa; Pieri, Elisa; Manathunga, Madushanka; Fusi, Stefania; Cappelli, Andrea; Latterini, Loredana; Pannacci, Danilo; Filatov, Michael; Léonard, Jérémie; Olivucci, Massimo;
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/jacs.5b10812.s003, doi: 10.1021/jacs.5b10812.s002
  • Subject: Molecular Biology | Protein Fluorophore Mimic | HBDI chromophore | Biotechnology | systems translocate | Transient spectroscopy | Genetics | nonadiabatic decay process | trajectory simulations show | Biophysics | CI nt | Neuroscience | Developmental Biology | charge transfer state | Medicine | cationic N | Computational Biology | conical intersection | Cell Biology | Biochemistry | Cancer | alkyl indanylidene pyrrolinium switch | Ultrafast Switching Function
    • FOR: 80699 Information Systems not elsewhere classified | 29999 Physical Sciences not elsewhere classified | 110309 Infectious Diseases | 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

While rotary molecular switches based on neutral and <i>cationic</i> organic π-systems have been reported, structurally homologous <i>anionic</i> switches providing complementary properties have not been prepared so far. Here we report the design and preparation ... View more
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