7-Azaindol-7-ylborate: A Novel Bidentate N^BH3 Chelating Ligand

Dataset UNKNOWN
Wagler, Jörg; Hill, Anthony F.;
(2008)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/om700871p.s003, doi: 10.1021/om700871p.s002, doi: 10.1021/om700871p.s001
  • Subject: sodium salt | Biotechnology | metal center | sodium borohydride | denticity | ligand | coordination | mode | Space Science | Azaindole | Chelating | Bidentate | azain | Medicine | requirement | anion | Rh | Biochemistry | NaBH 4 | azaindol | rhodium derivatives
    • FOR: 80699 Information Systems not elsewhere classified | 59999 Environmental Sciences not elsewhere classified | 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

7-Azaindole (H-azain) reacts with sodium borohydride (NaBH<sub>4</sub>) to yield the sodium salt of the novel 7-azaindol-7-ylborate anion (7-azain-7)BH<sub>3</sub><sup>−</sup>, two rhodium derivatives of which reveal distinct coordination modes  [Rh{κ<sup>2</sup><i>N</... View more
Share - Bookmark

  • Download from
    figshare via figshare (Dataset, 2008)
  • Cite this research data