Robust Multifunctional Yttrium-Based Metal–Organic Frameworks with Breathing Effect

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Firmino, Ana D. G.; Mendes, Ricardo F.; Antunes, Margarida M.; Barbosa, Paula C.; Vilela, Sérgio M. F.; Valente, Anabela A.; M. L. Figueiredo, Filipe; P. C. Tomé, João; A. Almeida Paz, Filipe;
(2017)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/acs.inorgchem.6b02199.s001, doi: 10.1021/acs.inorgchem.6b02199.s002, doi: 10.1021/acs.inorgchem.6b02199.s003
  • Subject: Biotechnology | compound 3 | Compound 2 | breathing effect | interconversion mechanism | SC | X-ray crystallography | ambient conditions | synthesis methodology | MOF materials | protonic conductivity | Microbiology | rehydration processes | bulk quantities | Computational Biology | Breathing Effect Phosphonate | proton conductors | Porous materials 2 | Structural flexibility | H 8 btp | Biochemistry | tetraphosphonate-based MOFs | 1 h | variable-temperature X-ray diffraction
    • FOR: 39999 Chemical Sciences not elsewhere classified

Phosphonate- and yttrium-based metal–organic frameworks (MOFs), formulated as [Y­(H<sub>5</sub>btp)]·5.5H<sub>2</sub>O (<b>1</b>), [Y­(H<sub>5</sub>btp)]·2.5H<sub>2</sub>O (<b>2</b>), (H<sub>3</sub>O)­[Y<sub>2</sub>(H<sub>5</sub>btp)­(H<sub>4</sub>btp)]·H<sub>2... View more
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