Spectroscopic and X-ray Crystallographic Evidence for Electrostatic Effects in 4-Substituted Cyclohexanone-Derived Hydrazones, Imines, and Corresponding Salts

Dataset UNKNOWN
Dibble, David J.; Ziller, Joseph W.; Woerpel, K. A.;
(2011)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/jo200950s.s002, doi: 10.1021/jo200950s.s003, doi: 10.1021/jo200950s.s004
  • Subject: pendant benzyloxy group | stabilization | Evidence | configuration | Imine | Sociology | iminium ion | derivative | conformation | Hydrazone | crystallography | solution | conformer | Spectroscopic | 1 H NMR spectroscopic analysis | model | conformationally | Biophysics | substrate | cyclohexanone hydrazone salts | polarity | charge | preference | Electrostatic Effects | Computational Biology | Hematology | SaltsThe | favor | Substituted | Biochemistry | molecule
    • FOR: 29999 Physical Sciences not elsewhere classified | 69999 Biological Sciences not elsewhere classified | 60506 Virology | 39999 Chemical Sciences not elsewhere classified

The axial conformer of several 4-substituted cyclohexanone hydrazone salts was found to predominate in solution. Changes in the charge of the molecule and the polarity of the solvent led to changes in the conformational preference of each molecule that were consistent w... View more
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