Cyano-Bridged Fe(II)–Cr(III) Single-Chain Magnet Based on Pentagonal Bipyramid Units: On the Added Value of Aligned Axial Anisotropy

Audiovisual, Dataset UNKNOWN
Pichon, Céline; Suaud, Nicolas; Duhayon, Carine; Guihéry, Nathalie; Sutter, Jean-Pascal;
(2018)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/jacs.8b03891.s002, doi: 10.1021/jacs.8b03891.s003, doi: 10.1021/jacs.8b03891.s004
  • Subject: Biotechnology | Neuroscience | building units | Pentagonal Bipyramid Units | anisotropy | Aligned Axial Anisotropy | compound | reversal | SMM | Cr 2 Fe | Biochemistry | ab initio modeling | SCM | Biophysics
    • FOR: 29999 Physical Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

A cyano-bridged Fe­(II)–Cr­(III) single-chain magnet designed to ensure a parallel orientation of the axial anisotropy of the building units is reported. This ferromagnetic chain compound consists of a pentagonal bipyramid Fe­(II) complex with Ising-type ani... View more
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