Proton-Induced Lewis Acidity of Unsaturated Iridium Amides

Dataset UNKNOWN
Heiden, Zachariah M.; Rauchfuss, Thomas B.;
(2006)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ja0653831.s002, doi: 10.1021/ja0653831.s001
  • Subject: 16 e cation | formation | ligand | Ecology | NH 3. 1 | CH 2Cl solution | 3CH | DPEN | Biophysics | novel organometallic Lewis acids | 3CPF | protonation | Microbiology | MeCN solution | CO | Cp | CH 2Cl solutions | Unsaturated Iridium AmidesOxidation | Cell Biology | species | Biochemistry | Ph | Cancer | H 2
    • FOR: 59999 Environmental Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

Oxidation of Cp*Ir((<i>rac</i>-TsDPEN)H (DPEN = H<sub>2</sub>NCHPhCHPhNTs) with Cp<sub>2</sub>FePF<sub>6</sub> or Ph<sub>3</sub>CPF<sub>6</sub> in MeCN solution generates [Cp*Ir(TsDPEN)(NCMe)]PF<sub>6</sub> ([<b>1</b>H(NCMe)]PF<sub>6</sub>) together with H<sub>2</sub> a... View more
Share - Bookmark

  • Download from
    figshare via figshare (Dataset, 2006)
  • Cite this research data