A Catalytic Enantioselective Tandem Allylation Strategy for Rapid Terpene Construction: Application to the Synthesis of Pumilaside Aglycon

Ferris, Grace E.; Hong, Kai; Roundtree, Ian A.; Morken, James P.;
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ja400506j.s007, doi: 10.1021/ja400506j.s004, doi: 10.1021/ja400506j.s003, doi: 10.1021/ja400506j.s006, doi: 10.1021/ja400506j.s005
  • Subject: Biotechnology | stereochemical course | diene | Sociology | diboration | Space Science | pumilaside aglycon | Biophysics | Immunology | carbocyclic reaction products | enantioselective | synthesis | Inorganic Chemistry | Rapid Terpene Construction | Catalytic Enantioselective Tandem Allylation Strategy | Pumilaside | AglyconCatalytic | Computational Biology | dicarbonyl | cascade allylborations | entry | application | Synthesi
    • FOR: 80699 Information Systems not elsewhere classified | 110309 Infectious Diseases

Catalytic enantioselective 1,2-diboration of 1,3-dienes followed by cascade allylborations with dicarbonyls provides rapid entry into carbocyclic reaction products. The stereochemical course of this reaction was studied along with its application in the synt... View more
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