Bis(1-cyanovinyl acetate) Is a Linear Precursor to 3‑Oxidopyrylium Ions

Dataset UNKNOWN
Wilkerson-Hill, Sidney Malik; Sawano, Shota; Sarpong, Richmond;
(2016)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/acs.joc.6b02111.s005, doi: 10.1021/acs.joc.6b02111.s002, doi: 10.1021/acs.joc.6b02111.s004, doi: 10.1021/acs.joc.6b02111.s003
  • Subject: Molecular Biology | complexity | Linear Precursor | diene | sp 3 | toluenesulfonate results | pyridinium p | sequential | bi | Plant Biology | Ion | acyl group transfers | 3- oxidopyrylium ions | approach | Bis | acetate | Ecology | 3- oxidopyrylium ion | precursor | dipolarophile | presence | Heating | Biophysics | Inorganic Chemistry | Oxidopyrylium | Herein | intramolecular cyclization event | trace amount | Cell Biology | cycloaddition | series | Biochemistry
    • FOR: 60506 Virology | 39999 Chemical Sciences not elsewhere classified

Herein we describe the first approach to 3-oxidopyrylium ions from a linear precursor. Heating bis­(1-cyanovinyl acetate) in the presence of a trace amount of pyridinium <i>p</i>-toluenesulfonate results in a series of acyl group transfers and an intramolecu... View more
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